文章摘要
三辛胺与磷酸三丁酯协同萃取盐酸介质中铼的研究
Synergistic extraction of rhenium(VII) from chloride media with mixtures of tri-alkylamine and tri-n-butylphosphate
投稿时间：2018-09-21  修订日期：2018-12-07
DOI：
中文关键词: 协同萃取，三辛胺，磷酸三丁酯，铼，钼
英文关键词: Synergistic extraction  tri-alkylamine  tri-n-butylphosphate  rhenium  molybdenum
基金项目:国家自然科学基金项目（面上项目，重点项目，重大项目）
作者单位邮编
张鹏 辽宁大学化学院 110036
王月娇 辽宁大学化学院 
张莹莹 辽宁大学化学院 
王丹丹 辽宁大学化学院 
刘毅 辽宁大学化学院 
娄振宁* 辽宁大学化学院 
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中文摘要:
      本文研究了在盐酸介质中，三辛胺（N235，R3N）与磷酸三丁酯（TBP，B）组成的协萃体系协同萃取铼的性能。N235-TBP协萃铼的能力强于钼，且在其摩尔浓度比为[N235]:[TBP]=1: 9时对钼铼的分离能力达到最大。与N235单独萃取体系中铼的萃合物组成（R3NH+ReO4-）不同，在pH = 1条件下，N235-TBP协萃体系中铼的萃合物组成为(R3NH+Cl-)2?HReO4?B，而在pH = 0.001条件下，该协萃体系中铼的萃合物组成为(R3NH+Cl-)?HReO4?B。此外，根据 N235-TBP协萃钼、铼的系列性能分析和探究，为钼体系中模拟料液的钼、铼分离提供依据。
英文摘要:
      The synergistic extraction of Rhenium(VII) from chloride media by mixtures of tri-alkylamine N235 and tri-n-butylphosphate TBP was studied in the present paper. The mixtures had higher synergistic effects on Re(VII) than that of Mo(VI), and the maximal synergistic factor was obtained at a ratio of N235 to TBP of 1 to 9. Re(VII) was extracted as (R3NH+Cl-)2.HReO4.B at pH = 1, whereas Re(VII) was extracted as (R3NH+Cl-).HReO4.B by the mixtures at pH = 0.001, instead of R3NH+ReO4- by N235 alone. Furthermore, the possibility of separating rhenium and molybdenum ions by the mixtures according to its synergistic effects and extraction ability was investigated.
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