| 孔令雅,林禄清.新型双膦配体合成及其铜(Ⅰ)配合物吸光性[J].,2023,63(2):111-118 |
| 新型双膦配体合成及其铜(Ⅰ)配合物吸光性 |
| Synthesis of novel bisphosphine ligands and absorptive property of copper(Ⅰ) complexes |
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| DOI：10.7511/dllgxb202302001 |
| 中文关键词: 手性 双膦配体 砌块 铜配合物 紫外可见光吸收光谱 |
| 英文关键词: chirality bisphosphine ligand building blocks copper complexes UV-Vis spectroscopy |
| 基金项目:辽宁省“兴辽英才计划”项目(XLYC1907126)；中央高校基本科研业务费专项资金资助项目(DUT20LK16). |
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| 中文摘要: |
| 基于C2对称性的手性联萘骨架，设计了一类新型双膦配体，并开发了一种简单、高效的汇聚式合成方法．该合成方法原料易得，可通过不同功能结构砌块之间的组合，对配体的电性和空间位阻进行调整．通过合成该类双膦配体的铜(Ⅰ)配合物，讨论了不同铜(Ⅰ)配合物吸光性的差异． |
| 英文摘要: |
| Based on the chiral C2-symmetric binaphthol-scaffold, a new class of bisphosphine ligands are developed. The bisphosphine ligands can be easily prepared from readily available compounds by newly developed, simple and efficient convergent synthesis. In addition, electron density and steric hindrance of ligands can be readily modified by installing various building blocks of structures with different functional groups. Some bisphosphine-ligated copper(Ⅰ) complexes are prepared and the difference in absorptive property of different copper(Ⅰ) complexes is discussed as well. |
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